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For a unit speed curve on a surface, the length of the surface-tangential component of acceleration is the geodesic
curvature 
.  Curves with 
 are called Geodesics.  For a curve parameterized
as 
, the geodesic curvature is given by
See also Geodesic
References
Gray, A.  ``Geodesic Curvature.''  §20.5 in
  Modern Differential Geometry of Curves and Surfaces.  Boca Raton, FL: CRC Press,
  pp. 402-407, 1993.