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N.B. A detailed on-line essay by S. Finch was the starting point for this entry.
Let 
 be the number of binary 
 Matrices with no adjacent 1s (in either columns
or rows).  Define 
, then the hard square entropy constant is defined by
References
Baxter, R. J.; Enting, I. G.; and Tsang, S. K.  ``Hard-Square Lattice Gas.''  J. Statist. Phys. 22, 465-489, 1980.
 
Finch, S.  ``Favorite Mathematical Constants.''  http://www.mathsoft.com/asolve/constant/square/square.html
 
Pearce, P. A. and Seaton, K. A.  ``A Classical Theory of Hard Squares.''  J. Statist. Phys. 53, 1061-1072, 1988.