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Let 
 be the set of all sets which are not members of themselves. Then 
 is neither a member of itself nor not a member
of itself. Symbolically, let 
.  Then 
 Iff 
. 
Bertrand Russell discovered this Paradox and sent it in a letter to G. Frege just as Frege was completing Grundlagen der Arithmetik. This invalidated much of the rigor of the work, and Frege was forced to add a note at the end stating, ``A scientist can hardly meet with anything more undesirable than to have the foundation give way just as the work is finished. I was put in this position by a letter from Mr. Bertrand Russell when the work was nearly through the press.''
See also Grelling's Paradox
References
Courant, R. and Robbins, H.  ``The Paradoxes of the Infinite.''  §2.4.5 in
  What is Mathematics?: An Elementary Approach to Ideas and Methods, 2nd ed.
  Oxford, England: Oxford University Press, p. 78, 1996.
 
Frege, G.  Foundations of Arithmetic.  Evanston, IL: Northwestern University Press, 1968.
 
Hofstadter, D. R.  Gödel, Escher, Bach: An Eternal Golden Braid.  New York: Vintage Books, pp. 20-21, 1989.