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A Set of Residues 
 (mod 
) such that every
Nonzero Residue can be uniquely expressed in the form 
.  Examples include
 (mod 7) and 
 (mod 13).  A Necessary condition for a difference set to exist is that
 be of the form 
.  A Sufficient condition is that 
 be a Prime Power.  Perfect sets can be used
in the construction of Perfect Rulers.
See also Perfect Ruler
References
Guy, R. K.  ``Modular Difference Sets and Error Correcting Codes.''  §C10 in 
  Unsolved Problems in Number Theory, 2nd ed.  New York: Springer-Verlag, pp. 118-121, 1994.